Ordained Bishop | Years | Name | Current Title |
| Most Senior |
| 6 Dec 1964 |
| Archbishop Eurico Dias Nogueira | Archbishop Emeritus of Braga, Portugal |
| 29 Jun 1967 |
| Archbishop Manuel Vieira Pinto | Archbishop Emeritus of Nampula |
| 21 May 1972 |
| Bishop Augusto César Alves Ferreira da Silva, C.M. | Bishop Emeritus of Portalegre-Castelo Branco, Portugal |
| 17 Dec 1972 |
| Bishop Luís Gonzaga Ferreira da Silva, S.J. | Bishop Emeritus of Lichinga |
| 9 Mar 1975 |
| Bishop Januário Machaze Nhangumbe | Bishop Emeritus of Pemba |
| 9 Mar 1975 |
| Alexandre José Maria Cardinal dos Santos, O.F.M. | Archbishop Emeritus of Maputo |
| 28 Mar 1976 |
| Archbishop Jaime Pedro Gonçalves | Archbishop Emeritus of Beira |
| 26 Sep 1976 |
| Bishop Paulo Mandlate, S.S.S. | Bishop Emeritus of Tete |
| 10 Oct 1976 |
| Bishop Bernardo Filipe Governo, O.F.M. Cap. | Bishop Emeritus of Quelimane |
| 24 Oct 1976 |
| Bishop Júlio Duarte Langa | Bishop Emeritus of Xai-Xai |
| 26 Jun 1988 |
| Bishop Francisco João Silota, M. Afr. | Bishop of Chimoio |
| 5 Apr 1990 |
| Archbishop Giacinto Berloco | Apostolic Nuncio to Belgium |
| Most Junior |
| 7 Oct 2012 |
| Archbishop Claudio Dalla Zuanna, S.C.I. | Archbishop of Beira |
| 10 Jul 2011 |
| Bishop João Carlos Hatoa Nunes | Auxiliary Bishop of Maputo |
| 22 May 2011 |
| Bishop Inácio Saure, I.M.C. | Bishop of Tete |
| 30 May 2010 |
| Bishop Francisco Lerma Martínez, I.M.C. | Bishop of Gurué |
| 22 Mar 2009 |
| Bishop Elio Giovanni Greselin, S.C.I. | Bishop of Lichinga |
| 24 Oct 2004 |
| Bishop Lucio Andrice Muandula | Bishop of Xai-Xai |
| 24 Oct 2004 |
| Bishop Ernesto Maguengue | Bishop Emeritus of Pemba |
| 20 Sep 2003 |
| Archbishop Antonio Arcari | Apostolic Nuncio to Mozambique |
| 15 Jun 2003 |
| Bishop Hilário da Cruz Massinga, O.F.M. | Bishop of Quelimane |
| 25 Feb 2001 |
| Archbishop Francisco Chimoio, O.F.M. Cap. | Archbishop of Maputo |
| 6 Jan 2000 |
| Archbishop George Panikulam | Apostolic Nuncio to Ethiopia |
| 22 Feb 1998 |
| Bishop Adriano Langa, O.F.M. | Bishop of Inhambane |