Ordained
Bishop | Years | Name | Current Title |
|---|
| Most Senior |
| 23 Nov 1974 |
| Archbishop Zacarias Kamwenho | Archbishop Emeritus of Lubango |
| 31 Aug 1975 |
| Alexandre Cardinal do Nascimento | Archbishop Emeritus of Luanda |
| 23 Nov 1986 |
| Archbishop José de Queirós Alves, C.SS.R. | Archbishop Emeritus of Huambo |
| 24 Jun 1990 |
| Bishop Serafim Shyngo-Ya-Hombo, O.F.M. Cap. | Bishop Emeritus of Mbanza Congo |
| 3 Mar 1996 |
| Eugenio Cardinal Dal Corso, P.S.D.P. | Bishop Emeritus of Benguela |
| 26 Aug 1996 |
| Archbishop Aldo Cavalli | Apostolic Visitor (Visitator) |
| 3 May 1998 |
| Bishop Anastácio Kahango, O.F.M. Cap. | Auxiliary Bishop Emeritus of Luanda |
| 6 Jan 2000 |
| Archbishop Gabriel Mbilingi, C.S.Sp. | Archbishop of Lubango |
| 1 Dec 2001 |
| Giovanni Angelo Cardinal Becciu | Prefect Emeritus of the Congregation for the Causes of Saints, Roman Curia |
| 3 Feb 2002 |
| Bishop Joaquim Ferreira Lopes, O.F.M. Cap. | Bishop Emeritus of Viana |
| 11 Jan 2004 |
| Archbishop Filomeno do Nascimento Vieira Dias | Archbishop of Luanda |
| 23 Oct 2005 |
| Bishop Almeida Kanda (Canda) | Bishop of Ndalatando |
| Most Junior |
| 23 Jun 2024 |
| Father Vicente Sanombo | Bishop-Elect of Kwito-Bié |
| 24 Feb 2024 |
| Archbishop Abel Liluala | Archbishop of Pointe-Noire, Congo |
| 3 Sep 2023 |
| Bishop Martín Lasarte Topolansky, S.D.B. | Bishop of Lwena |
| 12 Aug 2023 |
| Archbishop Germano Penemote | Apostolic Nuncio to Pakistan |
| 23 Jul 2023 |
| Bishop Firmino David | Bishop of Sumbe |
| 6 Feb 2022 |
| Bishop Estêvão Binga | Auxiliary Bishop of Benguela |
| 30 Jan 2022 |
| Bishop Fernando Francisco | Auxiliary Bishop of Luanda |
| 23 Jan 2022 |
| Bishop António Lungieki Pedro Bengui | Auxiliary Bishop of Luanda |
| 7 Mar 2021 |
| Bishop Joaquim Nhanganga Tyombe | Bishop of Uije |
| 17 Oct 2020 |
| Archbishop Giovanni Gaspari | Apostolic Nuncio to Korea |
| 16 Aug 2020 |
| Bishop Maurício Agostinho Camuto, C.S.Sp. | Bishop of Caxito |
| 12 May 2019 |
| Bishop Leopoldo Ndakalako | Bishop of Menongue |
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