Ordained
Bishop | Years | Name | Current Title |
|---|
| Most Senior |
| 6 Dec 1964 |
| Archbishop Eurico Dias Nogueira | Archbishop Emeritus of Braga, Portugal |
| 30 Apr 1967 |
| Bishop José Francisco Moreira dos Santos, O.F.M. Cap. | Bishop Emeritus of Uije |
| 23 Nov 1974 |
| Archbishop Zacarias Kamwenho | Archbishop Emeritus of Lubango |
| 2 Feb 1975 |
| Bishop Oscar Lino Lopes Fernandes Braga | Bishop Emeritus of Benguela |
| 31 Aug 1975 |
| Alexandre Cardinal do Nascimento | Archbishop Emeritus of Luanda |
| 28 Sep 1975 |
| Archbishop Francisco Viti | Archbishop Emeritus of Huambo |
| 29 Jul 1979 |
| Bishop Pedro Luís António | Bishop Emeritus of Kwito-Bié |
| 16 Oct 1983 |
| Bishop Pedro Luís Guido Scarpa, O.F.M. Cap. | Bishop Emeritus of Ndalatando |
| 23 Nov 1986 |
| Archbishop José de Queirós Alves, C.SS.R. | Archbishop of Huambo |
| 3 Jul 1988 |
| Bishop Fernando Guimarães Kevanu | Bishop Emeritus of Ondjiva |
| 24 Jun 1990 |
| Bishop Serafim Shyngo-Ya-Hombo, O.F.M. Cap. | Bishop Emeritus of Mbanza Congo |
| 6 Jul 1991 |
| Archbishop Félix del Blanco Prieto | Almoner Emeritus of the Office of Papal Charities, Roman Curia |
| Most Junior |
| 3 Mar 2013 |
| Bishop Estanislau Marques Chindekasse, S.V.D. | Bishop of Dundo |
| 12 Aug 2012 |
| Bishop Zeferino Zeca Martins, S.V.D. | Auxiliary Bishop of Luanda |
| 19 Feb 2012 |
| Bishop Pio Hipunyati | Bishop of Ondjiva |
| 2 Oct 2011 |
| Bishop José Manuel Garcia Cordeiro | Bishop of Bragança-Miranda, Portugal |
| 4 Sep 2011 |
| Bishop Dionísio Hisilenapo | Bishop of Namibe |
| 18 Mar 2010 |
| Archbishop Novatus Rugambwa | Apostolic Nuncio to São Tomé and Príncipe |
| 8 Mar 2009 |
| Bishop Vicente Carlos Kiaziku, O.F.M. Cap. | Bishop of Mbanza Congo |
| 14 Dec 2008 |
| Archbishop José Manuel Imbamba | Archbishop of Saurimo |
| 2 Mar 2008 |
| Bishop Jesús Tirso Blanco, S.D.B. | Bishop of Lwena |
| 22 Jul 2007 |
| Bishop António Francisco Jaca, S.V.D. | Bishop of Caxito |
| 25 Feb 2007 |
| Bishop Emílio Sumbelelo | Bishop of Uije |
| 23 Oct 2005 |
| Bishop Almeida Kanda (Canda) | Bishop of Ndalatando |
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