Ordained
Bishop | Years | Name | Current Title |
|---|
| Most Senior |
| 7 May 1972 |
| Bishop Juan Luis Ysern de Arce | Bishop Emeritus of San Carlos de Ancud |
| 27 May 1979 |
| Bishop Alejandro Goić Karmelić | Bishop Emeritus of Rancagua |
| 18 May 1980 |
| Bishop Manuel Camilo Vial Risopatrón, P. Schönstatt | Bishop Emeritus of Temuco |
| 19 Dec 1982 |
| Bishop Miguel Caviedes Medina | Bishop Emeritus of Los Angeles |
| 9 Mar 1986 |
| Archbishop Pablo Lizama Riquelme | Archbishop Emeritus of Antofagasta |
| 9 Sep 1989 |
| Bishop Rafael de la Barra Tagle, S.V.D. | Prelate Emeritus of Illapel |
| 6 Jan 1991 |
| Francisco Javier Cardinal Errázuriz Ossa, P. Schönstatt | Archbishop Emeritus of Santiago de Chile |
| 14 Apr 1991 |
| Archbishop Cristián Caro Cordero | Archbishop Emeritus of Puerto Montt |
| 15 Aug 1991 |
| Bishop Luis Gleisner Wobbe | Auxiliary Bishop Emeritus of La Serena |
| 8 Sep 1991 |
| Bishop Pedro Felipe Bacarreza Rodríguez | Bishop Emeritus of Santa Maria de Los Ángeles |
| 5 Jul 1992 |
| Bishop Cristián Enrique Contreras Molina, O. de M. | Bishop Emeritus of San Felipe |
| 2 Apr 1995 |
| Bishop Gonzalo Duarte García de Cortázar, SS.CC. | Bishop Emeritus of Valparaíso |
| Most Junior |
| 9 Nov 2024 |
| Bishop Mario Andrés Salas Becerra, O. de M. | Auxiliary Bishop of Valparaíso |
| 15 Jun 2024 |
| Bishop Enrique José Balzan Caruana | Auxiliary Bishop of La Serena |
| 18 Aug 2023 |
| Bishop Tomás Abel Carrasco Cortés | Bishop of San Juan Bautista de Calama |
| 1 Jul 2023 |
| Bishop Luis Alberto Migone Repetto | Auxiliary Bishop of Santiago de Chile |
| 10 Oct 2022 |
| Bishop Álvaro Chordi Miranda, Adsis | Auxiliary Bishop of Santiago de Chile |
| 6 Aug 2022 |
| Bishop Gustavo Adolfo Rosales Escobar | Bishop of San Jacinto, Ecuador |
| 18 Jun 2022 |
| Bishop Isauro Ilises Covili Linfati, O.F.M. | Bishop of Iquique |
| 30 Apr 2022 |
| Bishop Óscar Walter García Barreto | Auxiliary Bishop of Concepción (Santissima Concezione) |
| 30 Apr 2022 |
| Bishop Bernardo Andrés Álvarez Tapia | Auxiliary Bishop of Concepción (Santissima Concezione) |
| 17 Oct 2021 |
| Archbishop Andrés Gabriel Ferrada Moreira | Secretary of the Dicastery for the Clergy, Roman Curia |
| 13 Aug 2021 |
| Bishop Carlos Alberto Godoy Labraña | Bishop of Osorno |
| 13 Aug 2021 |
| Bishop Cristián Castro Toovey | Bishop of Santa Maria de Los Ángeles |
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