Ordained Bishop | Years | Name | Current Title |
| Most Senior |
| 2 Feb 1954 |
| Bishop José de Almeida Batista Pereira | Bishop Emeritus of Guaxupé, Minas Gerais |
| 15 Aug 1954 |
| Eugênio Cardinal de Araújo Sales | Archbishop Emeritus of São Sebastião do Rio de Janeiro |
| 28 Oct 1956 |
| Bishop José Bezerra Coutinho | Bishop Emeritus of Estância, Sergipe |
| 20 Jan 1957 |
| Archbishop Jaime Luiz Coelho | Archbishop Emeritus of Maringá, Parana |
| 22 Sep 1957 |
| Archbishop José Maria Pires | Archbishop Emeritus of Paraíba, Paraiba |
| 10 Nov 1957 |
| Bishop José Eugênio Corrêa | Bishop Emeritus of Caratinga, Minas Gerais |
| 13 Apr 1958 |
| Bishop José de Aquino Pereira | Bishop Emeritus of São José do Rio Preto, Sao Paulo |
| 27 Jul 1958 |
| Bishop Augusto Petró | Bishop Emeritus of Uruguaiana, Rio Grande do Sul |
| 10 Aug 1958 |
| Bishop Caetano Antônio Lima dos Santos, O.F.M. Cap. | Bishop Emeritus of Ilhéus, Baia |
| 7 May 1959 |
| Serafim Cardinal Fernandes de Araújo | Archbishop Emeritus of Belo Horizonte, Minas Gerais |
| 27 Mar 1960 |
| Bishop Epaminondas José de Araújo | Bishop Emeritus of Palmeira dos Índios, Alagoas |
| 25 Jul 1960 |
| Bishop Clemente José Carlos de Gouvea Isnard, O.S.B. | Bishop Emeritus of Nova Friburgo, Rio de Janeiro |
| Most Junior |
| 27 Sep 2008 |
| Bishop Antônio Emidio Vilar, S.D.B. | Bishop of São Luíz de Cáceres, Mato Grosso |
| 17 Aug 2008 |
| Bishop Francisco de Assis Dantas de Lucena | Bishop of Guarabira, Paraiba |
| 15 Aug 2008 |
| Bishop Romualdo Matias Kujawski | Coadjutor Bishop of Porto Nacional, Tocatins |
| 15 Aug 2008 |
| Bishop Philip Dickmans | Bishop of Miracema do Tocantins, Tocatins |
| 10 Aug 2008 |
| Bishop Jorge Alves Bezerra, S.S.S. | Bishop of Jardim, Mato Grosso do Sul |
| 2 Aug 2008 |
| Bishop Antônio Carlos Rossi Keller | Bishop of Frederico Westphalen, Rio Grande do Sul |
| 27 Jul 2008 |
| Bishop Irineu Gassen, O.F.M. | Bishop of Vacaria, Rio Grande do Sul |
| 5 Jul 2008 |
| Bishop Benedito Gonçalves dos Santos | Bishop of Presidente Prudente, Sao Paulo |
| 17 May 2008 |
| Bishop Guido Zendron | Bishop of Paulo Afonso, Baia |
| 17 May 2008 |
| Bishop Juarez Sousa Da Silva | Bishop of Oeiras, Piaui |
| 17 May 2008 |
| Bishop Adair José Guimarães | Bishop of Rubiataba-Mozarlândia, Goias |
| 19 Apr 2008 |
| Bishop Tarcísio Scaramussa, S.D.B. | Auxiliary Bishop of São Paulo, Sao Paulo |