Ordained
Bishop | Years | Name | Current Title |
|---|
| Most Senior |
| 20 Jan 1957 |
| Archbishop Jaime Luiz Coelho | Archbishop Emeritus of Maringá, Parana |
| 22 Sep 1957 |
| Archbishop José Maria Pires | Archbishop Emeritus of Paraíba, Paraiba |
| 10 Aug 1958 |
| Bishop Caetano Antônio Lima dos Santos, O.F.M. Cap. | Bishop Emeritus of Ilhéus, Baia |
| 7 May 1959 |
| Serafim Cardinal Fernandes de Araújo | Archbishop Emeritus of Belo Horizonte, Minas Gerais |
| 28 Aug 1960 |
| Archbishop Armando Círio, O.S.I. | Archbishop Emeritus of Cascavel, Parana |
| 29 Oct 1961 |
| Archbishop Antônio Ribeiro de Oliveira | Archbishop Emeritus of Goiânia, Goias |
| 6 Jan 1962 |
| Bishop José Mauro Ramalho de Alarcón Santiago | Bishop Emeritus of Iguatú, Ceara |
| 1 May 1964 |
| Bishop Waldyr Calheiros Novaes (de Novais) | Bishop Emeritus of Barra do Piraí-Volta Redonda, Rio de Janeiro |
| 3 Jul 1966 |
| Paulo Evaristo Cardinal Arns, O.F.M. | Archbishop Emeritus of São Paulo, Sao Paulo |
| 28 Aug 1966 |
| Archbishop Pedro Antônio Marchetti Fedalto | Archbishop Emeritus of Curitiba, Parana |
| 2 Oct 1966 |
| Archbishop Luciano José Cabral Duarte | Archbishop Emeritus of Aracajú, Sergipe |
| 6 Nov 1966 |
| Bishop Manuel Edmilson da Cruz | Bishop Emeritus of Limoeiro do Norte, Ceara |
| Most Junior |
| 22 Jul 2013 |
| Bishop José Aparecido Gonçalves de Almeida | Auxiliary Bishop of Brasília, Distrito Federal |
| 7 Jul 2013 |
| Bishop Luiz Antônio Cipolini | Bishop of Marília, Sao Paulo |
| 26 May 2013 |
| Bishop Marco Aurélio Gubiotti | Bishop of Itabira-Fabriciano, Minas Gerais |
| 18 May 2013 |
| Bishop Gabriele Marchesi | Bishop of Floresta, Pernambuco |
| 28 Apr 2013 |
| Bishop José Mário Scalon Angonese | Auxiliary Bishop of Curitiba, Parana |
| 16 Mar 2013 |
| Bishop Valdir Mamede | Auxiliary Bishop of Brasília, Distrito Federal |
| 3 Feb 2013 |
| Bishop Darci José Nicioli, C.SS.R. | Auxiliary Bishop of Aparecida, Sao Paulo |
| 30 Dec 2012 |
| Bishop Elio Rama, I.M.C. | Bishop of Pinheiro, Maranho |
| 27 Dec 2012 |
| Bishop Eraldo Bispo da Silva | Bishop of Patos, Paraiba |
| 30 Nov 2012 |
| Bishop Vital Corbellini | Bishop of Marabá, Para |
| 24 Nov 2012 |
| Bishop João Francisco Salm | Bishop of Tubarão, Santa Catarina |
| 15 Sep 2012 |
| Bishop José Eudes Campos do Nascimento | Bishop of Leopoldina, Minas Gerais |
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