Ordained Bishop | Years | Name | Current Title |
| Most Senior |
| 15 Aug 1954 |
| Eugênio Cardinal de Araújo Sales | Archbishop Emeritus of São Sebastião do Rio de Janeiro |
| 20 Jan 1957 |
| Archbishop Jaime Luiz Coelho | Archbishop Emeritus of Maringá, Parana |
| 22 Sep 1957 |
| Archbishop José Maria Pires | Archbishop Emeritus of Paraíba, Paraiba |
| 10 Aug 1958 |
| Bishop Caetano Antônio Lima dos Santos, O.F.M. Cap. | Bishop Emeritus of Ilhéus, Baia |
| 7 May 1959 |
| Serafim Cardinal Fernandes de Araújo | Archbishop Emeritus of Belo Horizonte, Minas Gerais |
| 28 Aug 1960 |
| Archbishop Armando Círio, O.S.I. | Archbishop Emeritus of Cascavel, Parana |
| 29 Oct 1961 |
| Archbishop Antônio Ribeiro de Oliveira | Archbishop Emeritus of Goiânia, Goias |
| 6 Jan 1962 |
| Bishop José Mauro Ramalho de Alarcón Santiago | Bishop Emeritus of Iguatú, Ceara |
| 1 May 1964 |
| Bishop Waldyr Calheiros Novaes (de Novais) | Bishop Emeritus of Barra do Piraí-Volta Redonda, Rio de Janeiro |
| 3 Jul 1966 |
| Paulo Evaristo Cardinal Arns, O.F.M. | Archbishop Emeritus of São Paulo, Sao Paulo |
| 28 Aug 1966 |
| Archbishop Pedro Antônio Marchetti Fedalto | Archbishop Emeritus of Curitiba, Parana |
| 2 Oct 1966 |
| Archbishop Luciano José Cabral Duarte | Archbishop Emeritus of Aracajú, Sergipe |
| Most Junior |
| 18 Mar 2012 |
| Bishop Rubens Sevilha, O.C.D. | Auxiliary Bishop of Vitória, Espirito Santo |
| 4 Mar 2012 |
| Bishop Joaquim Wladimir Lopes Dias | Auxiliary Bishop of Vitória, Espirito Santo |
| 12 Feb 2012 |
| Bishop João Santos Cardoso | Bishop of São Raimundo Nonato, Piaui |
| 11 Feb 2012 |
| Bishop João Justino de Medeiros Silva | Auxiliary Bishop of Belo Horizonte, Minas Gerais |
| 24 Sep 2011 |
| Bishop Gilson Andrade da Silva | Auxiliary Bishop of São Salvador da Bahia |
| 12 Aug 2011 |
| Bishop Marek Marian Piatek, C.SS.R. | Prelate of Coari, Amazonas |
| 22 Jul 2011 |
| Bishop Ettore Dotti, C.S.F. | Bishop of Naviraí, Mato Grosso do Sul |
| 9 Jul 2011 |
| Bishop Júlio Endi Akamine, S.A.C. | Auxiliary Bishop of São Paulo, Sao Paulo |
| 1 Jul 2011 |
| Bishop Wilson Luís Angotti Filho | Auxiliary Bishop of Belo Horizonte, Minas Gerais |
| 4 Jun 2011 |
| Bishop Benedito Araújo | Bishop of Guajará-Mirim, Rondonia |
| 8 May 2011 |
| Bishop Teodoro Mendes Tavares, C.S.Sp. | Auxiliary Bishop of Belém do Pará, Para |
| 29 Apr 2011 |
| Bishop José Francisco Falcão de Barros | Auxiliary Bishop of Brazil, Military |