| Date | Age | Event | Bishop | Title | Current Title |
|---|
| 11 Dec 2004 | 89.4 | Died | Tomás Enrique Márquez Gómez † | Bishop Emeritus of San Felipe |
| 30 Dec 2004 | 55.1 | Appointed | Freddy Jesús Fuenmayor Suárez | Bishop of Los Teques |
| 72.5 | Resigned | Ramón Ovidio Pérez Morales | Bishop of Los Teques | Bishop Emeritus |
| 24 Feb 2005 | 63.5 | Appointed | Giacinto Berloco | Apostolic Nuncio to Venezuela |
| 65.0 | Appointed | André Pierre Louis Dupuy | Apostolic Nuncio to European Community |
| 14 Jul 2005 | 77.5 | Died | José Vicente Henriquez Andueza, S.D.B. † | Bishop Emeritus of Maracay |
| 26 Jul 2005 | 54.4 | Appointed | William Enrique Delgado Silva | Bishop of Cabimas |
| 19 Sep 2005 | 63.1 | Appointed | Jorge Liberato Urosa Savino | Cardinal, Archbishop of Caracas, Santiago de Venezuela |
| 5 Nov 2005 | 63.2 | Installed | Jorge Liberato Urosa Savino | Cardinal, Archbishop of Caracas, Santiago de Venezuela |
| 12 Dec 2005 | 76.1 | Retired | Roberto Antonio Dávila Uzcátegui | Auxiliary Bishop of Caracas, Santiago de Venezuela | Auxiliary Bishop Emeritus |
| 24 Mar 2006 | 63.6 | Appointed | Jorge Liberato Urosa Savino | Cardinal-Priest of S. Maria ai Monti | Cardinal, Archbishop of Caracas, Santiago de Venezuela |
| 63.6 | Elevated to Cardinal | Jorge Liberato Urosa Savino | Cardinal, Archbishop of Caracas, Santiago de Venezuela |
| 2 Jul 2006 | 63.8 | Installed | Jorge Liberato Urosa Savino | Cardinal-Priest of S. Maria ai Monti | Cardinal, Archbishop of Caracas, Santiago de Venezuela |
| 11 Jul 2006 | 66.4 | Appointed | André Pierre Louis Dupuy | Apostolic Nuncio to Monaco | Apostolic Nuncio to European Community |
| 15 Jul 2006 | 48.6 | Appointed | José Luis Azuaje Ayala | Bishop of El Vigia-San Carlos del Zulia |
| 23 Sep 2006 | 48.8 | Installed | José Luis Azuaje Ayala | Bishop of El Vigia-San Carlos del Zulia |
| 9 Feb 2007 | 58.7 | Appointed | Luis Armando Tineo Rivera | Auxiliary Bishop of Caracas, Santiago de Venezuela |
| 58.7 | Appointed | Luis Armando Tineo Rivera | Titular Bishop of Horrea Coelia | Auxiliary Bishop of Caracas, Santiago de Venezuela |
| 10 Apr 2007 | 55.1 | Appointed | Reinaldo del Prette Lissot | Archbishop of Valencia en Venezuela |
| 28 Apr 2007 | 59.0 | Ordained Bishop | Luis Armando Tineo Rivera | Titular Bishop of Horrea Coelia | Auxiliary Bishop of Caracas, Santiago de Venezuela |
| 10 May 2007 | 90.7 | Died | Rafael Angel González Ramírez † | Bishop Emeritus of Barinas |
| 9 Jun 2007 | 63.6 | Appointed | Leonardo Sandri | Cardinal, Prefect of the Congregation for the Oriental Churches |
| 30 Jun 2007 | 55.7 | Appointed | Cástor Oswaldo Azuaje Pérez, O.C.D. | Auxiliary Bishop of Maracaibo |
| 55.7 | Appointed | Cástor Oswaldo Azuaje Pérez, O.C.D. | Titular Bishop of Vertara | Auxiliary Bishop of Maracaibo |
| 31 Aug 2007 | 55.9 | Ordained Bishop | Cástor Oswaldo Azuaje Pérez, O.C.D. | Titular Bishop of Vertara | Auxiliary Bishop of Maracaibo |
| 15 Oct 2007 | 46.8 | Appointed | Jesús González de Zárate Salas | Auxiliary Bishop of Caracas, Santiago de Venezuela |
| 46.8 | Appointed | Jesús González de Zárate Salas | Titular Bishop of Suava | Auxiliary Bishop of Caracas, Santiago de Venezuela |
| 16 Oct 2007 | 85.1 | Died | Rosalio José Castillo Lara, S.D.B. † | Cardinal, President Emeritus of the Pontifical Commission for Vatican City State |
| 24 Nov 2007 | 64.0 | Appointed | Leonardo Sandri | Cardinal-Deacon of S. Biagio e Carlo ai Catinari | Cardinal, Prefect of the Congregation for the Oriental Churches |
| 64.0 | Elevated to Cardinal | Leonardo Sandri | Cardinal, Prefect of the Congregation for the Oriental Churches |
| 2 Dec 2007 | 64.0 | Installed | Leonardo Sandri | Cardinal-Deacon of S. Biagio e Carlo ai Catinari | Cardinal, Prefect of the Congregation for the Oriental Churches |
| 22 Dec 2007 | 75.1 | Retired | Tulio Manuel Chirivella Varela | Archbishop of Barquisimeto | Archbishop Emeritus |
| 62.5 | Appointed | Antonio José López Castillo | Archbishop of Barquisimeto |
| 12 Jan 2008 | 47.0 | Ordained Bishop | Jesús González de Zárate Salas | Titular Bishop of Suava | Auxiliary Bishop of Caracas, Santiago de Venezuela |
| 12 Feb 2008 | 64.6 | Appointed | Rafael Ramón Conde Alfonzo | Bishop of Maracay |
| 26 Apr 2008 | 64.8 | Installed | Rafael Ramón Conde Alfonzo | Bishop of Maracay |
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