Ordained
Bishop | Years | Name | Current Title |
|---|
| Most Senior |
| 14 Sep 1958 |
| Bishop Antonio José Ramírez Salaverría | Bishop Emeritus of Maturín |
| 25 Mar 1965 |
| Bishop Eduardo Herrera Riera | Bishop Emeritus of Carora |
| 21 May 1967 |
| Bishop Francisco de Guruceaga Iturriza | Bishop Emeritus of La Guaira |
| 19 Mar 1971 |
| Archbishop Ramón Ovidio Pérez Morales | Bishop Emeritus of Los Teques |
| 25 Jul 1972 |
| Archbishop Medardo Luis Luzardo Romero | Archbishop of Ciudad Bolívar |
| 10 Sep 1972 |
| Bishop Roberto Antonio Dávila Uzcátegui | Auxiliary Bishop Emeritus of Caracas, Santiago de Venezuela |
| 9 Jun 1974 |
| Archbishop Tulio Manuel Chirivella Varela | Archbishop Emeritus of Barquisimeto |
| 25 Jul 1974 |
| Bishop Vicente Ramón Hernández Peña | Bishop of Trujillo |
| 20 Jan 1978 |
| Bishop José Joaquín Troconis Montiel | Auxiliary Bishop Emeritus of Valencia en Venezuela |
| 11 Sep 1979 |
| Bishop Miguel Delgado Avila, S.D.B. | Bishop Emeritus of Barcelona |
| 18 May 1980 |
| Archbishop Helímenas de Jesús Rojo Paredes, C.I.M. | Archbishop Emeritus of Calabozo |
| 19 Mar 1982 |
| Bishop José de Jesús Nuñez Viloria | Bishop Emeritus of Ciudad Guayana |
| Most Junior |
| 12 Jan 2008 |
| Bishop Jesús González de Zárate Salas | Auxiliary Bishop of Caracas, Santiago de Venezuela |
| 31 Aug 2007 |
| Bishop Cástor Oswaldo Azuaje Pérez, O.C.D. | Auxiliary Bishop of Maracaibo |
| 28 Apr 2007 |
| Bishop Luis Armando Tineo Rivera | Auxiliary Bishop of Caracas, Santiago de Venezuela |
| 22 May 2004 |
| Bishop Ramón José Aponte Fernández | Bishop of Valle de la Pascua |
| 27 Feb 2004 |
| Bishop Ulises Antonio Gutiérrez Reyes, O. de M. | Bishop of Carora |
| 7 Feb 2004 |
| Bishop Ramón José Viloria Pinzón, S.O.D. | Bishop of Puerto Cabello |
| 31 Oct 2003 |
| Bishop Enrique Pérez Lavado | Bishop of Maturín |
| 12 Sep 2003 |
| Bishop Iwannis Louis Awad | Vicar Apostolic of Venezuela, Faithful of the Oriental Rite (Syrian) |
| 15 Mar 2003 |
| Bishop Jesús Tomás Zárraga Colmenares | Bishop of San Carlos de Venezuela |
| 12 Jan 2002 |
| Bishop Luis Alfonso Márquez Molina, C.I.M. | Auxiliary Bishop of Mérida |
| 16 Dec 2001 |
| Archbishop Denys Antoine Chahda | Archbishop of Alep (Syrian), Syria |
| 16 Feb 2001 |
| Bishop José Hernán Sánchez Porras | Bishop of Venezuela, Military |
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