Ordained
Bishop | Years | Name | Current Title |
|---|
| 5 Jan 1969 |
| Archbishop Joachim N’Dayen | Archbishop Emeritus of Bangui |
| 19 Nov 1978 |
| Bishop Armando Umberto Gianni, O.F.M. Cap. | Bishop Emeritus of Bouar |
| 27 Oct 1991 |
| Bishop Agostino Giuseppe Delfino, O.F.M. Cap. | Bishop Emeritus of Berbérati |
| 6 Jan 1993 |
| Archbishop Diego Causero | Apostolic Nuncio Emeritus to Switzerland |
| 29 Oct 1995 |
| Bishop Guerrino Perin, M.C.C.I. | Bishop of Mbaïki |
| 29 Oct 1995 |
| Archbishop Paulin Pomodimo | Archbishop Emeritus of Bangui |
| 29 Oct 1995 |
| Bishop Jean-Claude Rembanga | Bishop Emeritus of Bambari |
| 26 Oct 1997 |
| Bishop François-Xavier Yombandje | Bishop Emeritus of Bossangoa |
| 10 May 1998 |
| Bishop Juan-José Aguirre Muñoz, M.C.C.I. | Bishop of Bangassou |
| 30 Oct 1999 |
| Archbishop Joseph Chennoth | Apostolic Nuncio to Japan |
| 6 Jan 2003 |
| Archbishop Pierre Nguyên Van Tot | Apostolic Nuncio to Sri Lanka |
| 3 Apr 2005 |
| Bishop Peter Marzinkowski, C.S.Sp. | Bishop Emeritus of Alindao |
| 28 Sep 2005 |
| Bishop Albert Vanbuel, S.D.B. | Bishop Emeritus of Kaga-Bandoro |
| 27 Sep 2008 |
| Archbishop Jude Thaddeus Okolo | Apostolic Nuncio to Ireland |
| 12 Sep 2009 |
| Archbishop Franco Coppola | Apostolic Nuncio to México |
| 22 Jul 2012 |
| Bishop Dennis Kofi Agbenyadzi, S.M.A. | Bishop of Berbérati |
| 22 Jul 2012 |
| Bishop Nestor-Désiré Nongo-Aziagbia, S.M.A. | Bishop of Bossangoa |
| 22 Jul 2012 |
| Dieudonné Cardinal Nzapalainga, C.S.Sp. | Archbishop of Bangui |
| 22 Jul 2012 |
| Bishop Cyr-Nestor Yapaupa | Bishop of Alindao |
| 15 Aug 2014 |
| Bishop Zbigniew Tadeusz Kusy, O.F.M. | Bishop of Kaga-Bandoro |
| 25 Mar 2017 |
| Bishop Bertrand Guy Richard Appora-Ngalanibé, O.P. | Bishop of Bambari |
| 10 Jun 2017 |
| Archbishop Santiago De Wit Guzmán | Apostolic Nuncio to Central African Republic |
| 12 Nov 2017 |
| Bishop Jesús Ruiz Molina, M.C.C.I. | Auxiliary Bishop of Bangassou |
| 11 Feb 2018 |
| Bishop Mirosław Gucwa | Bishop of Bouar |
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