| Ordained Bishop | Years | Name | Current Title |
|---|---|---|---|
| 18 Jun 1989 | Archbishop Luigi Bressan | Archbishop Emeritus of Trento, Italy | |
| 11 Aug 1993 | Jean-Baptiste (Gioan Baotixita) Cardinal Phạm Minh Mẫn | Archbishop Emeritus of Thành-Phô Hồ Chí Minh (Hôchiminh Ville), Viet Nam | |
| 6 Jan 1999 | Archbishop Salvatore Pennacchio | President of the Pontifical Ecclesiastical Academy, Roman Curia | |
| 6 Jan 2002 | Archbishop Giovanni d’Aniello | Apostolic Nuncio to Russian Federation | |
| 6 Jan 2003 | Archbishop Paul Tschang In-Nam | Apostolic Nuncio | |
| 18 Feb 2003 | Bishop Stephanus Tri Bữu Thiên | Bishop Emeritus of Cần Thơ, Viet Nam | |
| 20 Mar 2010 | Bishop Olivier Michel Marie Schmitthaeusler, M.E.P. | Vicar Apostolic of Phnom-Penh | |
| 19 Mar 2016 | Archbishop Peter Bryan Wells | Apostolic Nuncio to Thailand | |
| 6 Sep 2025 | Bishop Pierre Suon Hangly | Coadjutor Vicar Apostolic of Phnom-Penh |
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