| Ordained Bishop | Years | Name | Current Title |
|---|---|---|---|
| 14 Dec 1985 | Archbishop Antonio Mattiazzo | Bishop Emeritus of Padova {Padua}, Italy | |
| 29 Apr 1995 | Archbishop Luigi Ventura | Apostolic Nuncio | |
| 25 Sep 1999 | Mario Cardinal Zenari | Apostolic Nuncio to Syria | |
| 26 Sep 1999 | Archbishop Michel Christian Cartatéguy, S.M.A. | Archbishop Emeritus of Niamey | |
| 26 Sep 1999 | Bishop Ambroise Ouédraogo | Bishop Emeritus of Maradi | |
| 28 Oct 2007 | Archbishop Vito Rallo | Apostolic Nuncio | |
| 9 Jun 2013 | Archbishop Djalwana Laurent Lompo | Archbishop of Niamey | |
| 2 Jun 2015 | Archbishop Piergiorgio Bertoldi | Apostolic Nuncio to Dominican Republic | |
| 15 Aug 2020 | Archbishop Michael Francis Crotty | Apostolic Nuncio to Nigeria | |
| 31 May 2025 | Bishop Ignatius Kanmurum Anipu, M. Afr. | Bishop of Maradi | |
| 15 Nov 2025 | Father Éric Soviguidi | Apostolic Nuncio to Burkina Faso |
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